webXRS
Quantum number, spin, eigenvalue (lower set of states), degeneracy
1 -1 1 0.0000000E+00 1
1 -1 2 1.600000 1
1 -1 3 1.950000 1
1 -1 4 1.950000 2
1 -1 5 2.600000 1
Quantum number, spin, eigenvalue (lower set of states), degeneracy
2 1 1 0.0000000E+00 1
2 1 2 1.600000 1
2 1 3 1.950000 1
2 1 4 1.950000 2
2 1 5 2.600000 1
time writing and diagonalizing valence Hamiltonian matrix 4.3000001E-04
ground state energies of each sector:
1 0.0000000E+00
2 0.0000000E+00
1 belongs to the ground state sector and has degeneracy 1
ground state energy: 0.0000000E+00 spin: -1
Ground state occupations
x^2-y^2 occupation: 1.00000000000000
z^2 occupation: 0.000000000000000E+000
xy occupation: 0.000000000000000E+000
xz occupation: 0.000000000000000E+000
yz occupation: 0.000000000000000E+000
2 belongs to the ground state sector and has degeneracy 1
ground state energy: 0.0000000E+00 spin: 1
Ground state occupations
x^2-y^2 occupation: 1.00000000000000
z^2 occupation: 0.000000000000000E+000
xy occupation: 0.000000000000000E+000
xz occupation: 0.000000000000000E+000
yz occupation: 0.000000000000000E+000
ground state is 2 -fold degenerate
time writing and diagonalizing core Hamiltonian matrix 1.6711000E-02
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Succesful End
Number of orbitals: 5
Number of holes: 1
Ncellsx= 1 Ncellsy= 1
Total Hilbert space: 10 choose 1 = 10
Valence spin-orbit coupling: 0.0000000E+00
Sector: Total Sz spin Number of States in Sector
1 : 2Sz = -1 : 5
2 : 2Sz = 1 : 5
Projected Hilbert space, states used:
1 5 5
2 5 5
Core hole total Hilbert space: ( 10 choose 0 )times (6 times
1 ) = 6
Core hole partitioned Hilbert space: 6
CH eigenstates used 6
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U: 7.520000
Uprime,J_H:
6.120000 0.7000000 for dx^2-y^2/dxy orbitals
5.520000 1.000000 for dx^2-y^2/dxz/yz orbitals
5.320000 1.100000 for dx^2-y^2/dz^2 orbitals
Condon-Shortly parameters used for 3d-3d [eV]:
F0= 6.000000 F_2= 0.2000000 F_4= 2.0000000E-02
Condon-Shortly parameters used for 3d-2p [eV]:
F0= 6.000000 F^2= 6.126000 G^1= 4.630000 G^3= 2.630000
Xtal field 10Dq [eV]: -1.666667 core hole spin orbit [eV]: 10.50000
spin exchange (4t^2/U) is 0.5319149
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Total time for run: 0.2948830 seconds.